The exsolution of magmatic hydrosaline chloride liquids   总被引：14，自引：0，他引：14  

Jim D. Webster   《Chemical Geology》2004,210(1-4):33-48

Hydrosaline liquid represents the most Cl-enriched volatile phase that occurs in magmas, and the exsolution of this phase has important consequences for processes of hydrothermal mineralization and for volcanic emission of Cl to the atmosphere. To understand the exsolution of hydrosaline liquids in felsic to mafic magmas, the volatile abundances and (Cl/H₂O) ratios of more than 1000 silicate melt inclusions (MI) have been compared with predicted and experimentally determined solubilities of Cl and H₂O and associated (Cl/H₂O) ratios of silicate melts that were saturated in hydrosaline chloride liquid with or without aqueous vapor in hydrothermal experiments. This approach identifies the minimum volatile contents and the values of (Cl/H₂O) at which a hydrosaline chloride liquid exsolves from any CO₂- or SO₂-poor silicate melt. Chlorine solubility is a strong function of melt composition, so it follows that Cl solubility in magmas varies with melt evolution. Computations show that the (Cl/H₂O) ratio of residual melt in evolving silicate magmas either remains constant or increases to a small extent with fractional crystallization. Consequently, the initial (Cl/H₂O) in melt that is established early during partial melting has important consequences for the exsolution of vapor, vapor plus hydrosaline liquid, or hydrosaline liquid later during the final stages of melt ascent, emplacement, and crystallization or eruption. It is demonstrated that the melt (Cl/H₂O) controls the type of volatile phase that exsolves, whereas the volatile abundances in melt control the relative timing of volatile phase exsolution (i.e., the time of earliest volatile exsolution relative to the rate of magma ascent and crystallization history).

Comparing melt inclusion compositions with experimentally determined (Cl/H₂O) ratios and corresponding volatile solubilities of hydrosaline liquid-saturated silicate melts suggests that some fractions of the eruptive, calc-alkaline dacitic magmas of the Bonnin and Izu arcs should have saturated in and exsolved hydrosaline liquid at pressures of 2000 bars. Application of these same melt inclusion data to the predicted volatile solubilities of Cu-, Au-, and Mo-mineralized, calc-alkaline porphyritic magmas suggests that the chemical evolution of dioritic magmas to more-evolved quartz monzonite compositions involves a dramatic reduction in Cl solubility that increases the probability of hydrosaline liquid exsolution. The prediction that quartz monzonite magmas should exsolve a hydrosaline chloride liquid, that is potentially mineralizing, is consistent with the general observation of metal-enriched, hypersaline fluid inclusions in the more felsic plutons of numerous porphyry copper systems. Moreover, comparing the volatile contents of melt inclusions from the potassic, alkaline magmas of Mt. Somma-Vesuvius with the predicted (Cl/H₂O) ratios of hydrosaline liquid-saturated melts having compositions similar to those of the volatile-rich, alkaline magmas associated with the orthomagmatic gold–tellurium deposits of Cripple Creek, Colorado, suggests that hydrosaline chloride liquid should have exsolved at Cripple Creek as the magmas evolved to phonolite compositions. This prediction is consistent with the well-documented role of Cl-enriched, mineralizing hydrothermal fluids at this major gold-mining district.  相似文献   

Stable carbon isotopic evidence for differences in the dietary origin of bone cholesterol, collagen and apatite: implications for their use in palaeodietary reconstruction     

Susan Jim  Richard P. Evershed 《Geochimica et cosmochimica acta》2004,68(1):61-72

Rats were raised on a variety of isotopically controlled diets comprising 20% C₃, C₄ or marine protein and C₃ and/or C₄ non-protein or energy (i.e. sucrose, starch and oil) macronutrients. Compound specific stable carbon isotope (δ¹³C) analysis was performed on the cholesterol isolated from the diet (n=7 ) and bone (n=15 ) of these animals and the values compared with bulk δ¹³C measurements of bone collagen and apatite. The dietary signals reflected by these three bone biochemical components were investigated using linear regression analysis. δ¹³C values of bone cholesterol were shown to reflect whole diet δ¹³C values, collagen to reflect mainly dietary protein values and apatite to reflect whole diet values. Further correlations between dietary protein-to-energy spacings (Δ¹³C_prot-engy = δ¹³C_protein - δ¹³C_energy) and whole diet-to-bone component fractionations (Δ¹³C_bcomp-wdiet = δ¹³C_{bone component} - δ¹³C_{whole diet}) indicates that for hypothetical diets where protein δ¹³C values are equal to energy values, fractionations between whole diet and bone biochemical fractions are -3.3‰ for cholesterol, +5.4‰ for collagen and +9.5‰ for apatite. Moreover, the narrow range of variation observed in apatite-to-cholesterol spacings (Δ¹³C_apat-bchol) suggests that cholesterol δ¹³C values can potentially also be used as an independent test for the isotopic integrity of apatite δ¹³C values. These insights into bone cholesterol, collagen and apatite dietary signals, diet-to-bone fractionations and bone component-to-bone component spacings provide the basis for more accurate interpretations of the dietary behaviour of archaeological populations and food webs when the δ¹³C analysis of bone is employed.  相似文献   

On the Composition of Airborne Particles Influenced by Emissions of the Volcano Popocatépetl in Mexico     

Jiménez  J. C.  Raga  G. B.  Baumgardner  D.  Castro  T.  Rosas  I.  Báez  A.  Morton  O. 《Natural Hazards》2004,31(1):21-37

A 17-day field campaign was carried out in April–May 1999 to determine thecontribution that gaseous volcanic emissions make to the compositionof solid particles,particularly to the presence and quantity of sulfates. Theexperimental site was located inTonantzintla (in the State of Puebla), only 30 km E from the volcanoPopocatépetl, whichhas been in an active phase since the end of 1993. An analysis ofthe carbon monoxide(CO) and sulfur dioxide (SO₂) in the ambient air identifiedvolcanic influence in 6 out ofthe 17 days sampled. Particles collected in an 8-stage cascadeimpactor were analyzed for inorganic ions (by liquid chromatography).A non-parametric test indicates asignificant difference on the total particle mass and thesulfate fraction between days withand without volcanic influence. This difference was predominantlyobserved in the stages that collect the smaller particles. Windsat 500 mb (roughly corresponding to thesummit of the volcano) indicate a westerly transport from thevolcano to the experimentalsite, even though surface winds do not show a clear signal ofsuch a transport. Back trajectories from the experimental site werecalculated and clearly indicated that air parcels on the daysindependently identified as with volcanic influence had indeed passed over the volcano.  相似文献   

Reaction-based modeling of quinone-mediated bacterial iron(III) reduction   总被引：1，自引：0，他引：1  

William D. Burgos  Yilin Fang  Gour-Tsyh Yeh  Byong-Hun Jeon 《Geochimica et cosmochimica acta》2003,67(15):2735-2748

This paper presents and validates a new paradigm for modeling complex biogeochemical systems using a diagonalized reaction-based approach. The bioreduction kinetics of hematite (α-Fe₂O₃) by the dissimilatory metal-reducing bacterium (DMRB) Shewanella putrefaciens strain CN32 in the presence of the soluble electron shuttling compound anthraquinone-2,6-disulfonate (AQDS) is used for presentation/validation purposes. Experiments were conducted under nongrowth conditions with H₂ as the electron donor. In the presence of AQDS, both direct biological reduction and indirect chemical reduction of hematite by bioreduced anthrahydroquinone-2,6-disulfonate (AH₂DS) can produce Fe(II). Separate experiments were performed to describe the bioreduction of hematite, bioreduction of AQDS, chemical reduction of hematite by AH₂DS, Fe(II) sorption to hematite, and Fe(II) biosorption to DMRB. The independently determined rate parameters and equilibrium constants were then used to simulate the parallel kinetic reactions of Fe(II) production in the hematite-with-AQDS experiments. Previously determined rate formulations/parameters for the bioreduction of hematite and Fe(II) sorption to hematite were systematically tested by conducting experiments with different initial conditions. As a result, the rate formulation/parameter for hematite bioreduction was not modified, but the rate parameters for Fe(II) sorption to hematite were modified slightly. The hematite bioreduction rate formulation was first-order with respect to hematite ”free“ surface sites and zero-order with respect to DMRB based on experiments conducted with variable concentrations of hematite and DMRB. The AQDS bioreduction rate formulation was first-order with respect to AQDS and first-order with respect to DMRB based on experiments conducted with variable concentrations of AQDS and DMRB. The chemical reduction of hematite by AH₂DS was fast and considered to be an equilibrium reaction. The simulations of hematite-with-AQDS experiments were very sensitive to the equilibrium constant for the hematite-AH₂DS reaction. The model simulated the hematite-with-AQDS experiments well if it was assumed that the ferric oxide “surface” phase was more disordered than pure hematite. This is the first reported study where a diagonalized reaction-based model was used to simulate parallel kinetic reactions based on rate formulations/parameters independently obtained from segregated experiments.  相似文献   

A New Observational Strategy to Search for Solar g-Modes     

I. Martín Mateos  I. González Hernández  A. Jiménez  S.J. Jiménez Reyes  J. Patrón  P.L. Pallé  F. Pérez Hernández  C. Régulo  T. Roca-Cortés 《Astrophysics and Space Science》1998,263(1-4):339-342

  相似文献   

3-D Helioseismology: Rings and Horizontal Flows     

J. Patrón  I. González Hernández  A. Jiménez  S.J. Jiménez Reyes  I. Martín  P.L. Pallé  F. Pérez Hernández  C. Régulo  T. Roca-Cortés 《Astrophysics and Space Science》1998,263(1-4):327-330

We investigate the conditions under which general scalar-tensor gravity theories relax towards General Relativity. We extend the work of Damour and Nordtvedt [2] by studying the effects of the inclusion of a cosmological potential term. When the universe is either radiation dominated or vacuum, we find that Einstein's gravity is indeed a cosmological attractor and, also, that the universe exhibits inflationary expansion. This latter feature provides another striking argument in favour of the inflationary paradigm, which in the present setting arises without the intervention of the usual inflaton field. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Kinematics and Stellar Populations of Seyfert Galaxies     

Luis Jiménez-Benito  Angeles Díaz  Roberto Terlevich  Elena Terlevich 《Astrophysics and Space Science》1998,263(1-4):111-114

We have analyzed high signal-to-noise spectra of 10 active galaxies in order to investigate the stellar populations of these objects and the kinematics of the gas and stars in their nuclei. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Recent protected-area designation in China: an evaluation of administrative and statutory procedures   总被引：3，自引：0，他引：3  

C. Y. Jim  Steve S. W. Xu 《The Geographical journal》2004,170(1):39-50

Past protected-area (PA) designation in China followed a centralized administrative approach with minimum participation of lower-echelon governments. A period of deregulation and decentralization in 1979–91 without the benefit of relevant legislation resulted in few designations and poor management. Responding to national and international encouragement to augment the conservation of natural resources, the central government enacted statutory procedures in 1991 to encourage and regulate PA establishments at different administrative levels of government. The study evaluates the effectiveness of the new procedures in fulfilling conservation objectives. The new legislative and administrative regime reinforces deregulation and decentralization by devolving designation power and shifting financial and management responsibilities to lower levels of government, and involving more scientists and objective site assessment in PA design and assessment. Problems have arisen in the designation process due to the omission of key biota and ecosystems, bypassing the scientific assessment stage, too much emphasis on non-conservation gains, ignoring the needs of local communities, escalating people–park conflicts, intensifying paper-park syndrome, and the conflicting role of experts. The recently designated Shimentai Provincial Rank Nature Reserve in a mountain area in south China served as a case study to illustrate the procedures and problems.  相似文献   

An empirical test of the competing destinations model   总被引：2，自引：0，他引：2  

Pingzhao Hu  Jim Pooler 《Journal of Geographical Systems》2002,4(3):301-323

 It has long been believed that properties of spatial structure have a strong effect on trip distribution, which thus leads to a bias in the estimated distance decay parameters of spatial interaction models. This paper is an attempt to identify to what extent the spatial structure effect affects the trip distribution and determine whether the incorporation of a term to account for the relative location of destinations into the conventional gravity models, results in a model that can more correctly represent the actual trip distribution. The main focus is on the comparison of the origin–specific estimates of the distance decay parameter, calibrated from the traditional production-constrained model and the production-constrained competing destinations model. The results show that the competing destinations model is superior to the conventional model in both reproducing the interaction flows and giving behavioral explanation to the distance decay parameters, but the essential aim of the competing destinations model to remove the map pattern from the distance decay parameters of the conventional model has not been identified. Received: 5 September 2001 / Accepted: 17 June 2002 We are grateful to Gloria. A. Swieczkowski for kindly providing the migration data. The authors also gratefully acknowledge the comments of the referees.  相似文献   

Through-Water Close Range Digital Photogrammetry in Flume and Field Environments   总被引：4，自引：0，他引：4  

Justin Butler  Stuart Lane  Jim Chandler  & Ekaterini Porfiri 《The Photogrammetric Record》2002,17(99):419-439

Measurement of the structure of gravel-bed river surfaces is crucial for understanding both bed roughness and the sediment entrainment process. This paper describes the use of close range digital photogrammetry to measure and monitor change occurring in submerged river gravel-beds in both flume and field environments. High-resolution digital elevation models (DEMs) were obtained and two-media (through air and water) techniques were used to correct for the e.ects of refraction at the air/water interface. Although suitable refractive models have been developed, the use of proprietary software to generate DEMs automatically introduces the problem of how to re-establish collinearity. A simple refraction correction algorithm based upon analytical geometry was developed and is described. This algorithm was designed for use after initial DEM acquisition and allows any photogrammetric software package to be used for data acquisition. Application of this algorithm led to improvements in DEM accuracy by reducing the systematic, depth-dependent bias caused by refraction
Research carried out in a flume environment allowed the algorithm to be tested by measuring a flooded and drained bed surface. Non-systematic differences between the "dry" and "wet" DEMs arose from reductions in stereomatching success in the two-media case. This effect was thought to be due to light attenuation and the introduction of residual parallax. Results suggest that close range digital photogrammetry can be used to extract high quality DEMs of submerged topography in both flume and field fluvial environments, which represents a particularly exciting development for fluvial geomorphologists  相似文献